I am in the middle of watching all the Breaking Bad episodes on Netflix, and most of the songs on this album would be great in various episodes:
Tonight's the Night: deals w/ consequences of drug use for user, which is not the main focus of the show, but is connected thematically.
http://www.youtube.com/watch?v=90idj5MaTjE
Speaking Out: contented love, calm before the storm (post baby's birth, pre separation)
http://www.youtube.com/watch?v=kWiZ23lwyrA
World on a String: Walter's "I'm Going through Changes"
http://www.youtube.com/watch?v=zSEFj_NRn8c
Borrowed Tune: interstitial, maybe cooking meth in the desert
http://www.youtube.com/watch?v=C5-Uqj8TwZk
Come On Baby, Let's Go Downtown: buying/selling drugs, druggies dealing w/ cops
http://www.youtube.com/watch?v=WaclLeX9yaA
Mellow my Mind: Jesse's post rehab struggle to find peace, "fish on the line": selling drugs to others in rehab
http://www.youtube.com/watch?v=Hic4KkQD-H8
Roll Another Number (For The Road): picking up after a defeat, alone on the road, deals going down
http://www.youtube.com/watch?v=K6aXlqPMEXk
Albuquerque: specific to the location of show and various character's need to escape themselves
http://www.youtube.com/watch?v=ppkrb0VhN9A
New Mama: self explanatory, mother/child, all is not what it seems
http://www.youtube.com/watch?v=OS2Yfe2_XwI
Lookout Joe: heady times in the fast lane, watch your step!
http://www.youtube.com/watch?v=4JZO69hhHeE
Tired Eyes: graphic fallout of drug deals gone wrong
http://www.youtube.com/watch?v=JcplDg32y7Q
Tonight's the Night (reprise): see above
http://www.youtube.com/watch?v=GFIcQU8K4AY
With video editing skills/tools and time, one could put together some clips which would get pulled down pretty quickly
